3F-PCP Crystal – crystal meth online3F

Buy 3F-PCP Crystal, Pincer ligands bearing XCX-type scaffolds (X = N, P, S) have gained a great deal of attention as they allow the isolation of well-designed metal complexes, resulting in appealing structural and stereoelectronic features. In the present work, we report on the synthesis and characterization of a novel series of OCO conformation pincer ligands based on aryl benzyl ether structures, [(ROCH₂)₂C₆H₄], which contain unreported aromatic terminal units, where R = 2,6-dimethylphenyl (3a), 2,5-dimethylphenyl

(3b), 2,4-dimethylphenyl (3c), [1,1′-biphenyl]-3-yl] (3d), [1,1′-biphenyl]-4-yl] (3e), and pentachlorophenyl (3f). Our rationale for choosing these fragments of aromatic derivatives (−OR terminal units) is to provide points of electronic modulation on the ligands as well as thermodynamic and kinetic properties. We accomplished the molecular structure of compounds 3a and 3e in the crystalline state by single-crystal X-ray structural analysis.